Good coffee > PS5
You’re not gonna like this but, it depends. Sony implemented some very unique tech into the PS5. So if a game was designed to fully exploit the PS5 capabilities, then your experience playing that game will be far inferior on PC (for now).
SOURCE: I own all the consoles, Steam Deck, gaming PC, GeForce Now Founders subscription, and a number of good coffee makers.
You’re not gonna like this but, some unique tech that makes a game look 5% better isn’t making the experience better than access to mods, or being able to play 30 years old games on the same machine as a new game, or being able to play on mouse+keyboard. Especially considering games that “exploit the PS5 capabilities” tend to be formulaic AAA games featuring gameplay mechanics that got boring 2 decades ago.